Since your file name specifies a "FRENCH.BRRip.x264" release, you likely need English (or other language) subtitles that match this specific encoding to ensure the timing is correct.
Rename the subtitle file to match your video file exactly (e.g., A.Golden.Widow.1969.FRENCH.BRRip.x264.srt ).
Open the video, right-click, select Subtitle > Sub Track , and choose your file.